smtp-user-enum
smtp-user-enum -U /usr/share/seclists/Usernames/top-usernames-shortlist.txt -t 192.168.229.56 -w 30
smtp-user-enum -U /usr/share/seclists/Usernames/xato-net-10-million-usernames-dup.txt -t postfish.offsec
also create your own dictionary to try with .